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Chemical analysis of late stages of pheomelanogenesis: conversion of dihydrobenzothiazine to a benzothiazole structure
Pigment Cell & Melanoma Research, 06/19/09
Ito S et al. - The results show that, DHBTCA accumulates after the disappearance of the cysteinyldopa isomers, DHBTCA is then oxidized by a redox exchange with dopaquinone to form ortho-quinonimine, which leads to the production of pheomelanin with a benzothiazine moiety, and the benzothiazine moiety gradually degrades to form a benzothiazole moiety.
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